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When I was young I thought it would all be easy (but I go on)
[http://archiveofourown.org/works/1046722] - - public:opalsong
Loki is Thor's sister, not his brother. The events of Thor go somewhat differently.
The Queen of Helheim and the Secret Agent
[http://archiveofourown.org/series/24232] - - public:opalsong
In which Darcy Lewis is actually Hel Lokisdottir, Queen of Helheim, and Phil Coulson is the badass secret agent we all know and love.